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51.
52.
Behnam Bahrami Abasali KhodadadiYadollah Mortazavi Mohamad Esmaieli 《Applied Surface Science》2011,257(23):9710-9716
We report the variation of yield and quality of carbon nanotubes (CNTs) grown by chemical vapor deposition (CVD) of methane on iron oxide-MgO at 900-1000 °C for 1-60 min. The catalyst was prepared by impregnation of MgO powder with iron nitrate, dried, and calcined at 300 °C. As calcined and unreduced catalyst in quartz reactor was brought to the synthesis temperature in helium flow in a few minutes, and then the flow was switched to methane. The iron oxide was reduced to iron nanoparticles in methane, while the CNTs were growing.TEM micrographs, in accordance with Raman RBM peaks, indicate the formation of mostly single wall carbon nanotubes of about 1.0 nm size. High quality CNTs with IG/ID Raman peak ratio of 14.5 are formed in the first minute of CNTs synthesis with the highest rate. Both the rate and quality of CNTs degrades with increasing CNTs synthesis time. Also CNTs quality sharply declines with temperature in the range of 900-1000 °C, while the CNTs yield passes through a maximum at 950 °C. About the same CNTs lengths are formed for the whole range of the synthesis times. A model of continuous emergence of iron nanoparticle seeds for CNTs synthesis may explain the data. The data can also provide information for continuous production of CNTs in a fluidized bed reactor. 相似文献
53.
Fluctuations induced extinction and stochastic resonance effect in a model of tumor growth with periodic treatment 总被引:1,自引:0,他引:1
We investigate a stochastic model of tumor growth derived from the catalytic Michaelis-Menten reaction with positional and environmental fluctuations under subthreshold periodic treatment. Firstly, the influences of environmental fluctuations on the treatable stage are analyzed numerically. Applying the standard theory of stochastic resonance derived from the two-state approach, we derive the signal-to-noise ratio (SNR) analytically, which is used to measure the stochastic resonance phenomenon. It is found that the weak environmental fluctuations could induce the extinction of tumor cells in the subthreshold periodic treatment. The positional stability is better in favor of the treatment of the tumor cells. Besides, the appropriate and feasible treatment intensity and the treatment cycle should be highlighted considered in the treatment of tumor cells. 相似文献
54.
本文介绍中微子质量测量的历史和现状。介绍太阳中微子丢失实验的结果和大气 μ中微子丢失实验结果。这些结果表明存在中微子振荡 ,即中微子具有质量。它是超出标准模型的信号。本文还介绍了 2 1世纪初研究中微子振荡的若干重要实验 ,例如长基线中微子振荡实验以及建造 μ子贮存环来产生高能电子中微子束进行中微子振荡的实验以及测量中微子振荡时的CP破坏的设想。 相似文献
55.
56.
S. Dimitrov R. Breton† D. MacDonald† J.D. Walker O. Mekenyan 《SAR and QSAR in environmental research》2013,24(3-4):445-455
An evaluation of the capability of organic chemicals to mineralize is an important factor to consider when assessing their fate in the environment. Microbial degradation can convert a toxic chemical into an innocuous one, and vice versa , or alter the toxicity of a chemical. Moreover, primary biodegradation can convert chemicals into stable products that can be difficult to mineralize. In this paper, we present some new results obtained on the basis of a recently developed probabilistic approach to modeling biodegradation based on microbial transformation pathways. The metabolic transformations and their hierarchy were calibrated by making use of the ready biodegradability data from the MITI-I test and expert knowledge for the most probable transformation pathways. A model was developed and integrated into an expert software system named CATABOL that is able to predict the probability of biodegradation of organic chemicals directly from their structure. CATABOL simulates the effects of microbial enzyme systems, generates the most plausible transformation pathways, and quantitatively predicts the persistence and toxicity of the biodegradation products. A subset of 300 organic chemicals were selected from Canada's Domestic Substances List and subjected to CATABOL to compare predicted properties of the parent chemicals with their respective first stable metabolite. The results show that most of the stable metabolites have a lower acute toxicity to fish and a lower bioaccumulation potential compared to the parent chemicals. In contrast, the metabolites appear to be generally more estrogenic than the parent chemicals. 相似文献
57.
G.T. Ankley O.G. Mekenyan V.B. Kamenska P.K. Schmieder S.P. Bradbury 《SAR and QSAR in environmental research》2013,24(2):365-377
Retinoic acid and associated derivatives comprise a class of endogenous hormones that bind to and activate different families of retinoic acid receptors (RARs, RXRs), and control many aspects of vertebrate development. Identification of potential RAR and RXR ligands is of interest both from a pharmaceutical and toxicological perspective. The recently developed COREPA (COmmon REactivity PAttern) algorithm was used to establish reactivity profiles for a limited data set of retinoid receptor ligands in terms of activation of three RARs ( f , g , n ) and an RXR ( f ). Conformational analysis of a training set of retinoids and related analogues in terms of thermodynamic stability of conformers and rotational barriers showed that these chemicals tend to be quite flexible. This flexibility, and the observation that relatively small energy differences between conformers can result in significant variations in electronic structure, highlighted the necessity of considering all energetically reasonable conformers in defining common reactivity profiles. The derived reactivity patterns for three different subclasses of the RAR ( f , g , n ) were similar in terms of their global electrophilicity (nucleophilicity) and steric parameters. However, the profile of active chemicals with respect to interaction with the RXR- f differed qualitatively from that of the RARs. Variations in reactivity profiles for the RAR versus RXR families would be consistent with established differences in their affinity for endogenous retinoids, likely reflecting functional differences in the receptors. 相似文献
58.
After a brief review of the muon g-2 status,we discuss hypothetical errors in the Standard Model prediction that might explain the present discrepancy with the experimental value.None of them seems likely.In particular,a hypothetical increase of the hadroproduction cross section in low-energy e+e-collisions could bridge the muon g-2 discrepancy,but it is shown to be unlikely in view of current experimental error estimates.If,nonetheless,this turns out to be the explanation of the discrepancy,then the 95% CL upper bound on the Higgs boson mass is reduced to about 135 GeV which,in conjunction with the experimental 114.4 GeV 95%CL lower bound,leaves a narrow window for the mass of this fundamental particle. 相似文献
59.
We develop a microscopic pedestrian-simulation model in which pedestrian positions are updated at discrete time steps. At each time step, each pedestrian probabilistically selects a direction of movement from a predetermined set according to a logit-type function that considers the dynamics of other pedestrians around, and then selects a step size that satisfies a certain distribution. We perform a number of field experiments on real intersecting pedestrian flows with four different angles. We then validate and calibrate the model using sample data on the deviation angles, step velocities, and velocity–density relations obtained from the experiments. 相似文献
60.
Shear banding occurs in the flow of complex fluids: various types of shear thinning and shear thickening micelle solutions
and liquid crystals. In order to cope with the strongly inhomogeneous interface between the bands, constitutive models used
in standard rheology must be supplemented by non-local terms. This leads rather generally to non-linear partial differential
equations of the reaction-diffusion type. We use this formalism in order to explain some observed experimental features and
as a guide for future research in this field.
Received: 17 May 1999/Accepted: 3 August 1999 相似文献